Electronic structure regulation of an ultra-thin MOF-derived NiSe<sub>2</sub>/NiS<sub>2</sub>@NC heterojunction for promoting the hydrogen evolution reaction

نویسندگان

چکیده

A Ni-MOF is used as a precursor to synthesize NiSe 2 /NiS @NC heterojunction with rich phase interfaces through selenization/sulfurization process. Overpotentials of 188 mV and 211 are achieved in acidic alkaline media at 10 mA cm −2 .

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

MOF-Derived Ultrathin Cobalt Phosphide Nanosheets as Efficient Bifunctional Hydrogen Evolution Reaction and Oxygen Evolution Reaction Electrocatalysts

The development of a highly efficient and stable bifunctional electrocatalyst for water splitting is still a challenging issue in obtaining clean and sustainable chemical fuels. Herein, a novel bifunctional catalyst consisting of 2D transition-metal phosphide nanosheets with abundant reactive sites templated by Co-centered metal-organic framework nanosheets, denoted as CoP-NS/C, has been develo...

متن کامل

Bulk layered heterojunction as an efficient electrocatalyst for hydrogen evolution

We describe the spontaneous formation of composite chalcogenide materials that consist of two-dimensional (2D) materials dispersed in bulk and their unusual charge transport properties for application in hydrogen evolution reactions (HERs). When MoS2 as a representative 2D material is deposited on transition metals (such as Cu) in a controlled manner, the sulfidation reactions also occur with t...

متن کامل

Current Modulation of a Heterojunction Structure by an Ultra-Thin Graphene Base Electrode

Graphene has been proposed as the current controlling element of vertical transport in heterojunction transistors, as it could potentially achieve high operation frequencies due to its metallic character and 2D nature. Simulations of graphene acting as a thermionic barrier between the transport of two semiconductor layers have shown cut-off frequencies larger than 1 THz. Furthermore, the use of...

متن کامل

Application of Pd-Substituted Ni-Al Layered Double Hydroxides for the Hydrogen Evolution Reaction

Clean production of hydrogen from electrochemical water splitting has been known as a green method of fuel production. In this work, electrocatalytic hydrogen evolution reaction (HER) was investigated at new prepared layered double hydroxides (LDH) in acidic solution. NiAl/carbon black (CB) LDH was monitored using x-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scannin...

متن کامل

Preparation of Ni-P-CeO2 electrode and study on electrocatalytic properties for hydrogen evolution reaction

In this study ternary Ni-P-CeO2 catalysts were first synthesized by the Co-electrodeposition method on a copper substrate and then characterized by means of microstructural and electrochemical techniques toward a hydrogen evolution reaction (HER). Also, for comparison other catalysts such as Ni-CeO2, Ni-P, and Ni were prepared and characterized by the same methods. The microstructure of the inv...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Materials advances

سال: 2022

ISSN: ['2633-5409']

DOI: https://doi.org/10.1039/d1ma01168e